With the result, Dortmund now sits third in the table, whereas Freiburg suffered its first defeat and slipped to the 11th spot.
Jiangsu were placed second in the group after the third round.
Dilana took center stage early on by scoring seven points in a row, while Yang Shuyu provided much-needed help beyond the arc. The duo combined for 17 points in the first quarter to propel Dongguan to a 22-13 advantage.
"Chile is always a very difficult opponent. Every time a new qualifying tournament begins there are different expectations. I'm seeing some new faces and also a few old ones. There are several players that have already had a lot of international experience," he added. Enditem
Yerry Mina's header put Everton back in front on the stroke of halftime and James rounded off an excellent individual display with two second half goals.
Despite the loss, Hebei coach Ma Tao expressed satisfaction with his players.
"Despite only one week, she has improved a lot since we met last time. She is very young, but she has got everything on the court. Last time in Strasbourg, she didn't go into the game so quickly and played not so steadily. But this time, I can feel her confidence has boosted after winning two rounds at a Grand Slam," said Zhang, who defeated Burel 6-3, 7-6(3) in the Strasbourg Open before coming to Paris.
Only four minutes later, Leipzig established a two-goal lead after Christopher Nkunku's cross into the penalty area found Angelino, who made no mistake to get his name on the scoresheet.
Trencin entered the new season with a triumph thanks to a strong second period, scoring four goals and breaking its opponent Detva in the process.
The game went into turmoil after that as Ciro Immobile was sent off in the 69th minute for slapping Arturo Vidal after being tripped by the Chilean, while Inter's midfielder Stefano Sensi also saw red in the dying minutes.
"I wasn't experienced at all then, that was my first match on a big stadium like that, so I was pretty stressed," Swiatek said of her fourth-round loss to Halep last year.